BS ISO 20411:2018
$142.49
Surface chemical analysis. Secondary ion mass spectrometry. Correction method for saturated intensity in single ion counting dynamic secondary ion mass spectrometry
| Published By | Publication Date | Number of Pages |
| BSI | 2018 | 24 |
This document specifies a method for determining the maximum count rate for an acceptable limit of divergence from linearity of the intensity scale in pulse counting magnetic sector-type secondary ion mass spectrometers or quadrupole secondary ion mass spectrometers. It uses a test based on depth profile analysis of two isotopes in a reference material which has a gradual concentration change between low and high concentration regimes. It also includes a correction method for saturated intensity caused by the dead time of the detector. The correction can increase the intensity range for 95 % linearity so that a higher maximum count rate can be employed for those spectrometers for which the relevant correction equations have been shown to be valid.
This document does not apply to time of flight mass spectrometers.
This document is only applicable to elements with minor isotopes. It is not applicable if the element is monoisotopic or contains isotopes with equal abundances.
PDF Catalog
| PDF Pages | PDF Title |
|---|---|
| 2 | National foreword |
| 6 | Foreword |
| 7 | Introduction |
| 9 | 1 Scope 2 Normative references 3 Terms and definitions |
| 10 | 4 Symbols and abbreviated terms |
| 11 | 5 Outline of method |
| 13 | 6 Procedure for evaluating intensity linearity 6.1 Obtaining reference sample 6.2 Setting the sample 6.3 Operating the instrument 6.3.1 Setting the ion beam and the mass analyser 6.3.2 Setting the charge compensation 6.3.3 Setting the ion detector 6.4 Acquiring the data |
| 14 | 6.5 Assessing the linearity without and with intensity correction 6.5.1 Interpolating the minor isotope intensity |
| 15 | 6.5.2 Correcting the ratio of the isotope abundance to the instrument transmittance |
| 16 | 6.5.3 Assessing the linearity of intensity 6.5.4 Correcting the saturated intensity |
| 19 | 6.5.5 Assessing the uncertainty of the data |
| 20 | 7 Reporting the results 8 Correcting saturated intensity to the measurement results of the analysis samples |
| 21 | Annex A (informative) Effect of the dead time correction with various instruments for VAMAS study |
| 23 | Bibliography |
